Silyl–Silylene Interplay in Cationic PSiP Pincer Complexes of Platinum
收藏NIAID Data Ecosystem2026-03-08 收录
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Herein we report the synthesis and spectroscopic observation of a Pt complex featuring a P2Si ligand containing a central silylene donor connected to phosphines via two o-arylene linkers. Species of the type (P2Si)PtR undergo a net 1,2-migration of R from Pt to Si, which leads to highly unsaturated Pt cations displaying only a very distant interaction with the weakly coordinating carborane anion.
创建时间：
2016-02-15
