Chemo‑, Regio‑, and Stereoselective Trifluoromethylation of Styrenes via Visible Light-Driven Single-Electron Transfer (SET) and Triplet–Triplet Energy Transfer (TTET) Processes
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https://figshare.com/articles/dataset/Chemo_Regio_and_Stereoselective_Trifluoromethylation_of_Styrenes_via_Visible_Light_Driven_Single_Electron_Transfer_SET_and_Triplet_Triplet_Energy_Transfer_TTET_Processes/2237800
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资源简介：
A process for tunable and chemo-,
regio-, and stereoselective photocatalytic
trifluoromethylation of styrenes was developed. Thermodynamically
stable E-trifluoromethylated alkenes were prepared
using Togni’s reagent in the presence of Ru(bpy)3Cl2·6H2O under visible light irradiation,
whereas less thermodynamically stable Z-trifluoromethylated
alkenes were obtained by employing Umemoto’s reagent and photocatalyst
Ir(ppy)3.
创建时间：
2014-11-07
