Diasteroselective and Enantioselective Ir-Catalyzed Allylic Substitutions of 1‑Substituted 1‑Fluoro-1-(arenesulfonyl)methylene Derivatives
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https://figshare.com/articles/dataset/Diasteroselective_and_Enantioselective_Ir-Catalyzed_Allylic_Substitutions_of_1_Substituted_1_Fluoro-1-_arenesulfonyl_methylene_Derivatives/5417446
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资源简介：
diasteroselective and enantioselective
Ir-catalyzed allylic substitutions
of 1-substituted 1-fluoro-1-(arenesulfonyl)methylene derivatives are
presented, which afford the fluorinated allyl products with two chirality
centers. The steric demand of 1-substituted 1-fluoro-1-(arenesulfonyl)methylene
derivatives and allylic substrates has a great influence on the dr values of these reactions. The transformation of the
branched allyl product into the fluorinated 3,4-dihydro-2H-pyrrole 1-oxide was discussed, as well.
创建时间：
2017-09-06
