Photochemical Production of Ethane from an Iridium Methyl Complex
收藏Figshare2017-05-02 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Photochemical_Production_of_Ethane_from_an_Iridium_Methyl_Complex/4960571
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资源简介：
An iridium methyl complex, [Cp*Ir(bpy)(CH3)]+, was prepared by electrophilic methylation of Cp*Ir(bpy) with CH3I and characterized electrochemically, photophysically, crystallographically, and computationally. Irradiation of the MLCT transition of [Cp*Ir(bpy)(CH3)]+ in the presence of CH3I in acetonitrile produces ethane, methane, propionitrile, and succinonitrile. A series of mechanistic studies indicates that C–C bond formation is mediated by free methyl radicals produced through monometallic photochemical homolysis of the Ir–CH3 bond.
创建时间：
2017-05-02
