Synthesis of Aryl anti-Vicinal Diamines via Aza-Brook Rearrangement-Initiated Nucleophilic Addition of α‑Silylamines to Imines
收藏Figshare2016-02-13 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Synthesis_of_Aryl_i_anti_i_Vicinal_Diamines_via_Aza_Brook_Rearrangement_Initiated_Nucleophilic_Addition_of_Silylamines_to_Imines/2180566
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An efficient protocol is described for the synthesis of vicinal diamines via aza-Brook rearrangement-initiated nucleophilic addition of α-silylamines to imines. Various symmetrical and unsymmetrical aryl diamine derivatives were prepared in moderate to high yields with high anti/syn diastereoselectivity.
创建时间：
2016-02-13
