Desulfurative Chlorination of Alkyl Phenyl Sulfides
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https://figshare.com/articles/dataset/Desulfurative_Chlorination_of_Alkyl_Phenyl_Sulfides/4614730
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资源简介：
The chlorination
of readily available secondary and tertiary alkyl
phenyl sulfides using (dichloroiodo)benzene (PhICl2) is reported. This mild and rapid nucleophilic chlorination is extended
to sulfa-Michael derived sulfides, affording elimination-sensitive
β-chloro carbonyl and nitro compounds in good yields. The chlorination
of enantioenriched benzylic sulfides to the corresponding inverted
chlorides proceeds with high stereospecificity, thus providing a formal
entry into enantioenriched chloro-Michael adducts. A mechanism implying
the formation of a dichloro-λ4-sulfurane intermediate
is proposed.
创建时间：
2017-02-02
