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Pyro without Fire: Synthesis, Structure, and Reactivity of a Dimeric Vanadyl Pyrophosphate Coordination Complex

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https://figshare.com/articles/dataset/Pyro_without_Fire_Synthesis_Structure_and_Reactivity_of_a_Dimeric_Vanadyl_Pyrophosphate_Coordination_Complex/2482462
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The complex {[(VIVO)­bipy­(H2O)]2(μ-P2O7)}·3H2O (2) was readily obtained as a nanocrystalline powder by one-pot synthesis under mild conditions. Single crystals of 2 were grown at room temperature over 2 months, and its structure was determined. Fundamental catalytic activity was proven for this species by testing for oxidation of benzyl alcohol in air.
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2012-10-01
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