Evidence for the Formation of Terminal Hydrides by Protonation of an Asymmetric Iron Hydrogenase Active Site Mimic
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https://figshare.com/articles/dataset/Evidence_for_the_Formation_of_Terminal_Hydrides_by_Protonation_of_an_Asymmetric_Iron_Hydrogenase_Active_Site_Mimic/3010570
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资源简介：
Treatment of [Fe2(μ-pdt)(CO)6] [pdt = S(CH2)3S] with dppe
(Ph2PCH2CH2PPh2) in refluxing toluene affords the asymmetric
complex [Fe2(μ-pdt)(CO)4(dppe)] (1). Protonation of 1 with HBF4−Et2O in CH2Cl2 gives at room temperature the μ-hydrido derivative
[Fe2(μ-pdt)(CO)4(dppe)(μ-H)](BF4) (2). Monitoring the reaction by
1H, 31P, and 13C NMR at low temperature reveals unambiguously
that the process of the protonation of 1 implies terminal hydride
intermediates.
创建时间：
2016-06-03
