Base-Promoted Decarboxylative Azo-Coupling: Construction of Unsymmetrical Azocarboranes
收藏Figshare2017-02-01 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Base-Promoted_Decarboxylative_Azo-Coupling_Construction_of_Unsymmetrical_Azocarboranes/4602376
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Base-promoted decarboxylative azo couplings of carboranyl carboxylic acids with diazo salts have been developed to provide trans-azocarboranes in high yields (up to 94%). This approach is simple, efficient, and compatible with various functional groups. Mechanistically, the coupling has been proven to proceed in a nonradical pathway, which is distinct from those classical decarboxylative couplings.
创建时间：
2017-02-01
