Preparation of Telluro- and Selenoalumoxanes under Mild Conditions
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https://figshare.com/articles/dataset/Preparation_of_Telluro_and_Selenoalumoxanes_under_Mild_Conditions/2433331
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Syntheses of the heavy chalcogen-containing alumoxanes [MeLAl(SeH)]2(μ-O) (4) and (MeLAl)2(μ-Te)(μ-O) (7) were accomplished by the reaction of (MeLAlH)2(μ-O) (2; MeL = HC[(CMe)N(2,4,6-Me3C6H2)]2–) with either red selenium or metallic tellurium. The aluminum hydrogenselenide [MeLAl(SeH)]2(μ-Se) (3) was also prepared from the reaction of red selenium and MeLAlH2 (1). All compounds were characterized by spectroscopic methods and X-ray diffraction studies. Density functional theory calculations were performed on 4 and 7.
创建时间：
2016-02-19
