Rh(II)-Catalyzed Reactions of Differentially Substituted Bis(diazo) Functionalities
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https://figshare.com/articles/dataset/Rh_II_Catalyzed_Reactions_of_Differentially_Substituted_i_Bis_i_diazo_Functionalities/2386072
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资源简介：
The chemoselective reaction of donor/acceptor (D/A) and acceptor/acceptor (A/A) diazo moieties in the same molecule was examined using 3-diazo-1-(ethyl 2-diazomalonyl)indolin-2-one under rhodium(II) catalysis. The D/A diazo group undergoes selective cyclopropanation as well as XH-insertion, leaving behind the second diazo group for a further intramolecular dipolar cycloaddition reaction.
创建时间：
2016-02-19
