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A Ferromagnetic Salicylaldoximate/Azide MnII2MnIII6 Cluster with an S = 17 Ground State and a Single-Molecule-Magnet Response

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Figshare2016-06-14 更新2026-04-29 收录
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https://figshare.com/articles/dataset/A_Ferromagnetic_Salicylaldoximate_Azide_Mn_sup_II_sup_sub_2_sub_Mn_sup_III_sup_sub_6_sub_Cluster_with_an_i_S_i_17_Ground_State_and_a_Single-Molecule-Magnet_Response/3405046
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One new MnII2MnIII6 cluster exhibiting an S = 17 spin ground state and single-molecule-magnet properties has been designed linking MnIII3-salicylaldoximate triangles and tetracoordinated MnII cations by means of end-on azido bridges. The ferromagnetic coupling has been rationalized as a function of their structural parameters.
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2016-06-14
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