Directed Formation of a Ferrocenyl-Decorated Organotin Sulfide Complex and Its Controlled Degradation
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资源简介：
Attachment
of ferrocenyl (Fc) units to an organo-functionalized precursor yielded
the Fc-decorated complex [(RFcSn)4Sn6S10] [1; RFc = CMe2CH2C(Me)N–NC(Me)Fc], which shows
different ligand dynamics in solution than in the solid state, as
confirmed by NMR spectroscopy and by cyclic and differential pulse
voltammetry. The addition of different amounts of hydrochloric acid
to a solution of 1 produced the derivatives [(RFcSnCl2)2S] (2) and [RFcSnCl3·HCl] (3), the latter of which
acts as a precursor to the formation/recovery of 2 or 1, respectively.
创建时间：
2016-02-18
