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Ferrocenyl-Functionalized Sn/Se and Sn/Te Complexes: Synthesis, Reactivity, Optical, and Electronic Properties

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https://figshare.com/articles/dataset/Ferrocenyl_Functionalized_Sn_Se_and_Sn_Te_Complexes_Synthesis_Reactivity_Optical_and_Electronic_Properties/2230606
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An adamantane-shaped, ferrocenyl-substituted tin selenide complex, [(FcSn)4Se6] (1; Fc = ferrocenyl), and a ferrocenyl-substituted tin telluride five-membered ring, [(Fc2Sn)3Te2] (2), were obtained upon treatment of FcSnCl3 with K2E (E = Se, Te). Complex 1 further reacts with Na2S·9H2O and [Cu­(PPh3)3Cl] to form a ternary complex, [(CuPPh3)6(S/Se)6(SnFc)2] (3). We discuss structures, optical and electrochemical properties as well as Mössbauer spectra.
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2016-02-16
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