Ruthenium-Catalyzed Regioselective [2 + 2 + 2] Cyclotrimerization of Trifluoromethyl Group Substituted Internal Alkynes
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https://figshare.com/articles/dataset/Ruthenium_Catalyzed_Regioselective_2_2_2_Cyclotrimerization_of_Trifluoromethyl_Group_Substituted_Internal_Alkynes/2686933
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资源简介：
It found that the Ru3(CO)12 coordinated with 2-(diphenylphosphino)benzonitrile (2-DPPBN) to effectively catalyze the [2 + 2 + 2] cyclotrimerization of the trifluoromethyl group substituted internal alkynes in high yields with up to >98% regioselectivity. Isolation of a ruthenacyclopentadiene was successful and confirmed that the complex is a reaction intermediate.
创建时间：
2016-02-23
