Raw data of molecular analyses (SEM-EDX, ATR-FTIR, Raman, and GC-MS) of adhesive residues from Morín Cave (Spain)

The dataset contains data collected as part of the Ancient Adhesives project under the European Union’s Horizon 2020 research and innovation programme Grant Agreement No. 678 804151 (Grant holder G.H.J.L.).It is being made public to act as supplementary data for a publication and for other researchers to use this data in their own work.The data in this dataset were collected at TUDelft, University of Cantabria, and Museum of Prehistory and Archaeology of Cantabria in 2023.This dataset contains:Raw data for SEM-EDX of 11 archaeological objects named: MOR2; MOR4; MOR9; MOR12; MOR13; MOR17; MOR22; MOR35; MOR42; MOR50: MOR59. The file format is .pdfRaw data for micro-Raman of 6 archaeological objects named MOR2; MOR4; MOR9; MOR13; MOR22; MOR59. Raw-data for micro-Raman of 5 experimentally recreated adhesive samples: pine tar, birch tar, pine resin, beeswax, pine resin+beeswax, Ppine resin+beeswax+hematite. The analysis was performed with 532 and 785 laser lines. The file formats are .txt and .csvRaw data for ATR-FTIR of 7 archaeological objects and 1 sediment sample named: MOR11; MOR38; MOR40a; MOR43; MOR44; MOR46; MOR47; MORSediment. The file format is .csvRaw data for GC-MS of 23 archaeological objects (including sub-samples) and 2 sediment samples named: 230404 MOR 1.1.sirslt; 230404 MOR 5.1.sirslt; 230404 MOR 14.1.sirslt; 230404 MOR 24.1.sirslt; 230404 MOR 26.1.sirslt; 230404 MOR 28.1.sirslt; 230404 MOR 32.1.sirslt; 230404 MOR 43.1.sirslt; 230404 MOR 49.1.sirslt; 230404 MOR 57.1.sirslt; 230404 MOR 58.1.sirslt; 230421 MOR 5a.s.sirslt; 230421 MOR 11.1.sirslt; 230421 MOR 40a.3.sirslt; 230421 MOR 45.1.sirslt; 230421 MOR 47.2.sirslt; 230421 MOR 61.1.sirslt; 230421 MOR62.2.sirslt; 20220718 MOR25_1.sirslt; 20220718 MOR25_2.sirslt; 20220718 MOR38_1.sirslt; 20220718 MOR38_2.sirslt; 20220718 MOR40a_1.sirslt; 20220718 MOR40a_2.sirslt; 20220718 MOR47_1.sirslt; 20230316 MOR_41.1.sirslt; 20230316 MOR_44.1.sirslt; 20230316 MOR_46.1.sirslt; 20230316 MOR_60.1.sirslt; 20231024_MOR_SED 10.sirslt. Each.sirslt file contains the files necessary to open and manipulate the data using the original software Agilent OpenLab 2.5. Within each file there is a .DX file (for opening with Agilent OpenLab 2.5) and accompanying .ACAML, .DX, .MFX, .BIN, .RX, .PMX, and .AMX files. In addition, a .xlsx file (Morin GC-MS results.xlsx) is provided. Each sheet contains the complete GC-MS data exported for samples analyzed as well as the MS data and automated molecular data against the National Institute of Standards and Technology (NIST) library.The acronym MOR stands for Morín<strong> </strong>Cave, a cave in Cantabria (Spain) where the objects were found.The data included in this dataset has been organized per method. For each specimen, more than one point was measured as indicated in the file name. Only the measurements with interpretable results are made available.The file name includes the unique ID of the object + the analytical technique + the number of the scan. For example: MOR11_ATR_loc1

本数据集源自欧盟地平线2020（Horizon 2020）研究与创新计划下的古代胶黏剂（Ancient Adhesives）项目，项目资助协议编号为678 804151，项目主持人为G.H.J.L.。本数据集公开发布，旨在为相关学术出版物提供补充数据，供其他研究人员在其研究工作中使用。
本数据集的采集工作于2023年在代尔夫特理工大学（TUDelft）、坎塔布里亚大学（University of Cantabria）以及坎塔布里亚史前与考古博物馆（Museum of Prehistory and Archaeology of Cantabria）完成。
本数据集包含以下内容：
1. 11件考古标本的扫描电子显微镜-能量色散X射线光谱仪（SEM-EDX）原始数据，标本编号依次为MOR2、MOR4、MOR9、MOR12、MOR13、MOR17、MOR22、MOR35、MOR42、MOR50、MOR59，文件格式为.pdf。
2. 6件考古标本的显微拉曼光谱原始数据，对应标本为MOR2、MOR4、MOR9、MOR13、MOR22、MOR59；另有5件实验复刻胶黏剂样品的显微拉曼光谱原始数据，样品分别为松焦油、桦木焦油、松树树脂、蜂蜡、松树树脂+蜂蜡以及松树树脂+蜂蜡+赤铁矿。本次分析采用532 nm与785 nm激光激发波长，文件格式为.txt与.csv。
3. 7件考古标本与1件沉积物样品的衰减全反射傅里叶变换红外光谱（ATR-FTIR）原始数据，标本及样品编号为MOR11、MOR38、MOR40a、MOR43、MOR44、MOR46、MOR47以及MORSediment，文件格式为.csv。
4. 23件考古标本（含子样本）与2件沉积物样品的气相色谱-质谱联用（GC-MS）原始数据，对应编号如下：230404 MOR 1.1.sirslt、230404 MOR 5.1.sirslt、230404 MOR 14.1.sirslt、230404 MOR 24.1.sirslt、230404 MOR 26.1.sirslt、230404 MOR 28.1.sirslt、230404 MOR 32.1.sirslt、230404 MOR 43.1.sirslt、230404 MOR 49.1.sirslt、230404 MOR 57.1.sirslt、230404 MOR 58.1.sirslt、230421 MOR 5a.s.sirslt、230421 MOR 11.1.sirslt、230421 MOR 40a.3.sirslt、230421 MOR 45.1.sirslt、230421 MOR 47.2.sirslt、230421 MOR 61.1.sirslt、230421 MOR62.2.sirslt、20220718 MOR25_1.sirslt、20220718 MOR25_2.sirslt、20220718 MOR38_1.sirslt、20220718 MOR38_2.sirslt、20220718 MOR40a_1.sirslt、20220718 MOR40a_2.sirslt、20220718 MOR47_1.sirslt、20230316 MOR_41.1.sirslt、20230316 MOR_44.1.sirslt、20230316 MOR_46.1.sirslt、20230316 MOR_60.1.sirslt、20231024_MOR_SED 10.sirslt。每个.sirslt格式文件包含可使用安捷伦OpenLab 2.5软件打开与处理数据所需的全部文件，其中包括用于安捷伦OpenLab 2.5的.dx文件，以及配套的.acaml、.dx、.mfx、.bin、.rx、.pmx与.amx文件。此外，本数据集还提供了名为Morin GC-MS results.xlsx的Excel文件，其每个工作表均包含对应分析样本导出的完整GC-MS数据，以及基于美国国家标准与技术研究院（National Institute of Standards and Technology, NIST）谱库匹配得到的质谱数据与自动解析的分子信息。
缩写MOR指代莫林洞穴（Morín Cave），该洞穴位于西班牙坎塔布里亚地区，为本研究中考古标本的出土地点。
本数据集已按分析方法进行分类整理。对于每件标本，均按照文件名标注的信息完成了多个测点的测试；本数据集仅公开具备可解释性的测试结果。文件名格式统一为：标本唯一ID+分析技术+扫描次数，例如：MOR11_ATR_loc1。