An Intramolecular [2 + 2] Photocycloaddition Approach to Conformationally Restricted Bis-Pyrrolidines
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https://figshare.com/articles/dataset/An_Intramolecular_2_2_Photocycloaddition_Approach_to_Conformationally_Restricted_Bis_Pyrrolidines/2269204
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资源简介：
With N-Boc-protected 4-(allylaminomethyl)-2(5H)furanones as starting materials, a photochemical approach
is presented to give 3,9-diazatricyclo[5.3.0.01,5]decanes
as conformationally restricted bis-pyrrolidines. The products are
orthogonally protected at the two nitrogen atoms and exhibit, depending
on the substitution pattern at positions C5, C6, and C7, latent C2 symmetry. When the furanones had a phenyl
group at the 3-position (X3), alternative photochemical
pathways were observed.
创建时间：
2016-02-17
