Activation of Ammonia by a Carbene-Stabilized Dithiolene Zwitterion
收藏NIAID Data Ecosystem2026-03-13 收录
下载链接：
https://figshare.com/articles/dataset/Activation_of_Ammonia_by_a_Carbene-Stabilized_Dithiolene_Zwitterion/20719443
下载链接
链接失效反馈官方服务：
资源简介：
A carbene-stabilized dithiolene zwitterion (3) activates
ammonia, affording 4• and 5, through both single-electron transfer (SET) and hydrogen
atom transfer (HAT). Reaction products were characterized spectroscopically
and by single-crystal X-ray diffraction. The mechanism of the formation
of 4• and 5 was probed by experimental and computational methods. This discovery
is the first example of metal-free ammonia activation via HAT.
创建时间：
2022-08-29
