Nickel-Catalyzed Intermolecular [3 + 2 + 2] Cocyclization of Ethyl Cyclopropylideneacetate and Alkynes. Synthesis of Seven-Membered Carbocycles
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https://figshare.com/articles/dataset/Nickel_Catalyzed_Intermolecular_3_2_2_Cocyclization_of_Ethyl_Cyclopropylideneacetate_and_Alkynes_Synthesis_of_Seven_Membered_Carbocycles/2972815
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资源简介：
The [3 + 2 + 2] cocyclization of ethyl cyclopropylideneacetate (1a) and various alkynes proceeded
smoothly in the presence of Ni(cod)2–PPh3. The cycloheptadiene derivatives were synthesized in highly
selective manners. The unique reactivity of 1a was essential for the progress of the reaction. The observed
regioselectivity of the product formation and the mechanism of the reaction are discussed.
创建时间：
2016-06-03
