Catalytic, Three-Component Assembly Reaction for the Synthesis of Pyrrolidines
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https://figshare.com/articles/dataset/Catalytic_Three-Component_Assembly_Reaction_for_the_Synthesis_of_Pyrrolidines/3748101
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资源简介：
Copper(I) salts catalyze the three-component assembly reaction between an α-diazo ester, an imine, and various alkenes and alkynes to form
substituted pyrrolidines with excellent to good diastereoselectivities in high yields. The transition metal-catalyzed decomposition of the α-diazo
compound in the presence of the imine likely generates a transient azomethine ylid that undergoes addition with various dipolarophiles in a
highly convergent manner.
创建时间：
2016-08-20
