Solvent-Controlled Quadruple Catenation of Giant Chiral [8+12] Salicylimine Cubes Driven by Weak Hydrogen Bonding [Data]
收藏DataCite Commons2023-08-23 更新2025-04-17 收录
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https://heidata.uni-heidelberg.de/citation?persistentId=doi:10.11588/data/TIYBD2
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资源简介：
A quadruply interlocked catenane has been formed from giant chiral [8+12] salicylimine cubes in a reaction that can be controlled by the reaction solvent. Single-crystal X-ray diffraction revealed hydrogen bonding to be a central driving force for the catenation. Furthermore, scrambling experiments with partially deuterated cages allowed mechanistic insights into the interlocking process.
提供机构：
heiDATA
创建时间：
2023-08-22
