Synthesis of β‑Hydroxysulfones from Sulfonyl Chlorides and Alkenes Utilizing Visible Light Photocatalytic Sequences
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https://figshare.com/articles/dataset/Synthesis_of_Hydroxysulfones_from_Sulfonyl_Chlorides_and_Alkenes_Utilizing_Visible_Light_Photocatalytic_Sequences/3188668
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资源简介:
The synthesis of
β-hydroxysulfones from sulfonyl chlorides
and styrenes in the presence of water by a visible light mediated
atom transfer radical addition (ATRA)-like process utilizing fac[Ir(ppy)3] as photoredox catalyst was developed
in high yields. This process could be combined with the visible light
mediated synthesis of trifluoromethylated sulfonyl chlorides via an
ATRA reaction between alkenes and CF3SO2Cl utilizing
[Cu(dap)2Cl] as photoredox catalyst, demonstrating the
possibility of sequential photoredox processes.
创建时间:
2016-05-02



