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Naphthodithiophenediimide (NDTI): Synthesis, Structure, and Applications

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https://figshare.com/articles/dataset/Naphthodithiophenediimide_NDTI_Synthesis_Structure_and_Applications/2389747
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A straightforward synthesis of α,β-unsubstituted and α-halogenated naphtho­[2,3-b:6,7-b′]­dithiophenediimides (NDTIs) is described. Electrochemical and optical studies of N,N-dioctyl-NDTI demonstrate that the compound has a low-lying LUMO energy level (4.0 eV below the vacuum level) and a small HOMO–LUMO gap (∼2.1 eV). With its interesting electronic and optical properties, in addition to its planar structure, NDTI is a promising building block for the development of novel π-functional materials. In fact, it afforded n-channel, p-channel, and ambipolar materials, depending on the molecular modification.
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2013-08-07
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