Synthesis, Structure, and Chemical Property of the First Fluorine-Containing Porphycene
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https://figshare.com/articles/dataset/Synthesis_Structure_and_Chemical_Property_of_the_First_Fluorine-Containing_Porphycene/3747372
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资源简介：
A pyrrolic macrocycle, β-tetrakis(trifluoromethyl)porphycene, is the first example of a fluorine-containing porphycene. Four electron-withdrawing
CF3 substituents provide a highly distorted structure and an attractive electron-deficient nature for the porphycene framework. From the
electrochemical study, it is found that the LUMO energy level for the β-trifluoromethylporphycene is 1.24 V more stabilized compared to that
for etioporphyrin. Moreover, the deprotonation of the inner N−H proton in the porphycene was observed upon the addition of DBU.
创建时间：
2016-08-20
