Selective Dehydrogenative Coupling of Ethylene to Butadiene via an Iridacyclopentane Complex
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https://figshare.com/articles/dataset/Selective_Dehydrogenative_Coupling_of_Ethylene_to_Butadiene_via_an_Iridacyclopentane_Complex/5841555
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资源简介：
An iridium complex is found to catalyze the selective dehydrogenative coupling of ethylene to 1,3-butadiene. The key intermediate, and a major resting state, is an iridacyclopentane that undergoes a surprisingly facile β-H elimination, enabled by a partial dechelation (κ3–κ2) of the supporting 3,5-dimethylphenyl-2,6-bis(oxazolinyl) ligand.
创建时间：
2018-02-01
