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Copper-Catalyzed Oxidative Ring Closure and Carboarylation of 2‑Ethynylanilides

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NIAID Data Ecosystem2026-03-08 收录
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https://figshare.com/articles/dataset/Copper_Catalyzed_Oxidative_Ring_Closure_and_Carboarylation_of_2_Ethynylanilides/2352844
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A new copper-catalyzed oxidative ring closure of ethynyl anilides with diaryliodonium salts was developed for the highly modular construction of benzoxazines bearing a fully substituted exo double bond. The oxidative transformation includes an unusual 6-exo-dig cyclization step with the formation of C–O and C–C bonds.
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2016-02-18
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