PdCl2-Catalyzed Oxidative Cycloisomerization of 3-Cyclopropylideneprop-2-en-1-ones
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https://figshare.com/articles/dataset/PdCl_sub_2_sub_Catalyzed_Oxidative_Cycloisomerization_of_3_Cyclopropylideneprop_2_en_1_ones/2517982
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资源简介：
A novel PdCl2-catalyzed oxidative cycloisomerization of 3-cyclopropylideneprop-2-en-1-ones, providing a facile synthesis of highly strained functionalized 2-alkylidenecyclobutanones via furan-fused cyclobutene intermediates, is reported. An interesting route to 2(3H)-furanones with a spiro-cyclopropane unit from the obtained 2-alkylidenecyclobutanones via a ring-contraction rearrangement reaction is also realized.
创建时间：
2016-02-20
