Synthesis, Structures, and Solution Dynamics of Functionalized Phosphinomethanide Complexes of the Alkali Metals
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https://figshare.com/articles/dataset/Synthesis_Structures_and_Solution_Dynamics_of_Functionalized_Phosphinomethanide_Complexes_of_the_Alkali_Metals/3763164
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资源简介：
Metathesis between [Li{(Me3Si)2C}P(C6H4-2-CH2NMe2)2] and NaOBut in ether yields the
sodium phosphinomethanide [Na{(Me3Si)2C}P(C6H4-2-CH2NMe2)2(Et2O)0.5(DME)0.5] (2b) after
recrystallization. Complex 2b and its Li and K analogues are highly fluxional in solution,
and the dynamic processes accounting for this have been studied by variable-temperature
1H NMR spectroscopy.
创建时间：
2016-08-26
