Mesoionic Carbene–Boranes
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https://figshare.com/articles/dataset/Mesoionic_Carbene_Boranes/2350690
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资源简介：
Mesoionic
carbenes (MICs), derived from alkylation and deprotonation
of triazoles, are shown to form stable complexes with BH3. The synthesis of triazoles via Huigsen cycloadditions provides
considerable structural diversity. Several routes to MIC–boranes
are described, and their structures have been characterized by X-ray
crystallography. As predicted on the basis of the increased σ-donor
capacity of MICs by comparison to NHCs, the MIC–borane adducts
are more reactive reducing agents.
创建时间：
2016-02-18
