Synthesis and Characterization of New Platinum(II) and Platinum(IV) Triphyrin Complexes
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https://figshare.com/articles/dataset/Synthesis_and_Characterization_of_New_Platinum_II_and_Platinum_IV_Triphyrin_Complexes/2442550
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资源简介：
Metalation of 6,13,20,21-tetrakis(4-methylphenyl)-22H-tribenzo[14]triphyrin(2.1.1) with PtCl2 gave
a platinum(II) complex having a square-planar coordination structure
with two pyrrolic nitrogen atoms and two chloride ions, with a saddle-shaped
macrocycle. This platinum(II) complex was easily oxidized by air to
an octahedral platinum(IV) complex coordinated by three pyrrolic nitrogen
atoms as a tridentate monoanionic cyclic ligand and three chloride
ions. When platinum(II) triphyrin was crystallized in air, an oxygen
atom was incorporated between two α-carbon atoms of the pyrroles
as an oxygen bridge to intercept the 14π aromatic system.
创建时间：
2013-02-18
