Three-Dimensional Silver-dabco Coordination Polymers with Zeolitic or Three-Connected Topology
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https://figshare.com/articles/dataset/Three_Dimensional_Silver_dabco_Coordination_Polymers_with_Zeolitic_or_Three_Connected_Topology/2239297
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资源简介：
The simple linear linking ligand
diazabicyclo[2.2.2]octane
(dabco) combines with silver(I) to form three-dimensional (3D) coordination
polymers which have either a zeolitic mtn topology structure
or a (10,3)-b ths network according to the counteranion
used. The tetrahedral anions BF4– or
ReO4– promote formation of [Ag(dabco)2]·X, which has a 3D four-connected mtn framework
of fused 512 and 64512 cages, and
the material shows modest absorption of iodine. The bulky anion [Co(C2B9H11)2]− and an excess of dabco promote formation of complex [Ag2(dabco)3(CH3CN)2]·2[Co(C2B9H11)2] with a three-connected
(10,3)-b network, while use of 1 equiv of dabco gives a previously
reported [Ag(dabco)]·[Co(C2B9H11)2], which has a one-dimensional coordination
chain structure.
创建时间：
2016-02-16
