First 3D Pr(III)−Ni(II)−Na(I) Polymer and A 3D Pr(III) Open Network Based on Pyridine-2,4,6-tricarboxylic Acid
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https://figshare.com/articles/dataset/First_3D_Pr_III_Ni_II_Na_I_Polymer_and_A_3D_Pr_III_Open_Network_Based_on_Pyridine_2_4_6_tricarboxylic_Acid/3242521
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资源简介：
The self-assembly of pyridine-2,4,6-tricarboxylic acid (H3ptc) with
metal salts under hydrothermal conditions gave two novel
coordination polymers, {[Pr(μ5-ptc)(H2O)2]·1.5H2O}n (1) and {Na2NiPr(μ4-ClO4)(μ2-HOCH2CH2OH)(μ4-ptc)2(H2O)8}·4.5H2O}n (2). 1
is a 3D open network with five ptc ligands coordinating with one
metal center and carboxylate groups linking metal centers to form
a (4,6) net. 2 is the first Pr/Ni/Na heterotrimetallic complex, a unique
3D framework containing four different bridged ligands in the
system.
创建时间：
2016-05-05
