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Synthesis of Small Carboranylsilane Dendrons as Scaffolds for Multiple Functionalizations

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NIAID Data Ecosystem2026-03-06 收录
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https://figshare.com/articles/dataset/Synthesis_of_Small_Carboranylsilane_Dendrons_as_Scaffolds_for_Multiple_Functionalizations/3057163
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Small carbosilane dendrons in which a closo-carborane is located at the focal point have been prepared by a sequence of steps involving hydrosilylation and reduction reactions. These compounds are used as scaffolds for peripheral functionalization with styrene, chlorovinylstyrene, or suitable carboranes, while keeping the Ccluster−Si (Cc−Si) bond. Modification of the core by reduction of the carborane with Mg/BrCH2CH2Br was also achieved.
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2006-09-28
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