C3- vs C10-Acylation of 9‑Methoxyphenanthrene Controlled by Non-Covalent Interactions
收藏NIAID Data Ecosystem2026-05-10 收录
下载链接：
https://figshare.com/articles/dataset/C3-_vs_C10-Acylation_of_9_Methoxyphenanthrene_Controlled_by_Non-Covalent_Interactions/31964018
下载链接
链接失效反馈官方服务：
资源简介：
An
approach to the regiodivergent acylation of the phenanthrene
skeleton has been developed for the first time in the literature.
C3- and C10-acylation products were obtained in good to high yields.
DFT calculations revealed that the unique regioselectivity was controlled
by Coulomb repulsion, π–π stacking, hydrogen bonding,
and steric effects. The mechanism was further verified via the synthesis
of naphthalene derivatives.
创建时间：
2026-04-08
