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Transformation between Diphosphinoamines and Iminobiphosphines: a Reversible PNP ↔ NP−P Rearrangement Triggered by Protonation/Deprotonation<sup>†</sup>

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NIAID Data Ecosystem2026-03-06 收录
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The protonation of diphosphinoamines attached to pyridine at the ortho-position quantitatively affords the corresponding iminobiphosphine isomers. The starting material can be recovered quantitatively by deprotonation with base. The system represents a new type of molecular switch.

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2016-05-07
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