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Remarkable Scan Rate Dependence for a Highly Constrained Dinuclear Iron(II) Spin Crossover Complex with a Wide Thermal Hysteresis Loop

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https://figshare.com/articles/dataset/Remarkable_Scan_Rate_Dependence_for_a_Highly_Constrained_Dinuclear_Iron_II_Spin_Crossover_Complex_with_a_Wide_Thermal_Hysteresis_Loop/2330089
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The abrupt [HS-HS] ↔ localized [HS-LS] spin crossovers of a new triazole-based diiron­(II) complex result in a record-equaling thermal hysteresis loop width for a dinuclear complex (ΔT = 22 K by SQUID magnetometer in “settle” mode) and show a remarkable scan rate dependence of only the cooling branch, as revealed by detailed magnetic, DSC, and Mössbauer studies.
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2016-02-18
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