Alkene Isomerization–Hydroboration Promoted by Phosphine-Ligated Cobalt Catalysts
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https://figshare.com/articles/dataset/Alkene_Isomerization_Hydroboration_Promoted_by_Phosphine_Ligated_Cobalt_Catalysts/2206093
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资源简介：
Generated
in situ from air-stable cobalt precursors or readily synthesized using
NaHBEt3, (PPh3)3CoH(N2) was found to be an effective catalyst for the hydroboration of
alkenes. Unlike previous base-metal catalysts for alkene isomerization–hydroboration
which favor the incorporation of boron at terminal positions, (PPh3)3CoH(N2) promotes boron incorporation
adjacent to π-systems even in substrates where the alkene is
at a remote position, enabling a unique route to 1,1-diboron compounds
from α,ω-dienes.
创建时间：
2016-02-15
