Secondary Phosphine Oxide–Gold(I) Complexes and Their First Application in Catalysis
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https://figshare.com/articles/dataset/Secondary_Phosphine_Oxide_Gold_I_Complexes_and_Their_First_Application_in_Catalysis/2266909
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A series of new secondary phosphine oxide (SPO)–gold(I) complexes have been synthesized and characterized by X-ray crystallography. Complexes exhibited dimeric structures interconnected by O–H···Cl hydrogen bonds. Their first use in homogeneous catalysis is reported and suggests a broad field of application in prototypical enyne cycloisomerization and hydroxy- and methoxycyclization reactions.
创建时间：
2016-02-17
