Formation of Cationic Intermediates upon the Activation of Bis(imino)pyridine Nickel Catalysts
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The activation of bis(imino)pyridine nickel(II) dichloride complexes [LNiCl2] with methylalumoxane (MAO) and AlMe3/[CPh3][B(C6F5)4] was studied by multinuclear NMR spectroscopy. Formation of similar outer-sphere ion pairs of the types [LNiMe]+[MeMAO]− and [LNiMe]+[B(C6F5)4]−, capable of promoting norbornene polymerization, was observed.
创建时间：
2016-02-19
