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Preparation and X-ray Structures of 3-[Bis(trifluoroacetoxy)iodo]benzoic Acid and 3-[Hydroxy(tosyloxy)iodo]benzoic Acid: New Recyclable Hypervalent Iodine Reagents

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https://figshare.com/articles/dataset/Preparation_and_X_ray_Structures_of_3_Bis_trifluoroacetoxy_iodo_benzoic_Acid_and_3_Hydroxy_tosyloxy_iodo_benzoic_Acid_New_Recyclable_Hypervalent_Iodine_Reagents/2964709
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资源简介:
Preparation, structural characterization, and reactivity of 3-[bis(trifluoroacetoxy)iodo]benzoic acid and 3-[hydroxy(tosyloxy)iodo]benzoic acid, new recyclable iodine(III) reagents derived from 3-iodosylbenzoic acid, are described. The reduced form of these reagents, 3-iodobenzoic acid, can be easily recovered from the reaction mixtures using ion-exchange resin or basic aqueous workup followed by acidification with HCl.
创建时间:
2008-01-04
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