Selective Formation of Heterometallic Ru–Ag Supramolecules via Stoichiometric Control of Multiple Different Tectons
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https://figshare.com/articles/dataset/Selective_Formation_of_Heterometallic_Ru_Ag_Supramolecules_via_Stoichiometric_Control_of_Multiple_Different_Tectons/2167348
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资源简介:
Stoichiometric
control of Ru, Ag, and tetrazolyl ligands resulted
in the formation of different heterometallic Ru–Ag supramolecular
architectures. Although the reaction of Ru and 5-(2-hydroxyphenyl)-1H-tetrazolyl (LH2) in a molar ratio of 2:1 or 6:4 resulted in the formation of dimeric
or hexameric Ru complexes, Ag metal ions caused the Ru complexes to
form three-dimensional cylindrical Ru6Ag6L6 and double-cone-shaped Ru6Ag8L6 complexes
by occupying vacant coordination sites.
创建时间:
2016-02-13



