Palladium(II)-Catalyzed Direct Regioselectively Oxidative Acylation of Azobenzenes with Toluene Derivatives
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A highly efficient and practical procedure to acylazobenzene via Pd-catalyzed oxidative C–H bond activation from toluene has been developed. Various mono- and diacylazobenzene were afforded simultaneously in moderate to excellent yields for 33 examples. Toluene and its derivatives were served as potential and ideal acylation reagents. The mono- and diacylated products could be controlled by the oxidant loading.
创建时间:
2016-02-17



