Evidence for Direct Transmetalation of AuIII–F with Boronic Acids
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https://figshare.com/articles/dataset/Evidence_for_Direct_Transmetalation_of_Au_sup_III_sup_F_with_Boronic_Acids/4033251
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资源简介：
The underlying reactivity of AuIII–F species with aryl boronic acids has been studied in detail taking advantage of four novel, stable difluoro-[(C^N)AuF2], arylmonofluoro-[(C^N)AuArF], and alkylmonofluoro-[(C^N)AuAlkF] gold(III) complexes, prepared and isolated in monomeric form. We provide the first experimental evidence for a direct AuIII–F/B transmetalation preceding the Csp2–Csp2 or Csp3–Csp2 bond formation.
创建时间：
2016-10-20
