Directing the Reactivity of [HFe4N(CO)12]− toward H+ or CO2 Reduction by Understanding the Electrocatalytic Mechanism
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Selective reactivity of an electrocatalytically generated catalyst–hydride intermediate toward the hydrogen evolution reaction (HER) or reduction of CO2 is key for a CO2 reduction electrocatalyst. Under appropriate conditions, Et4N[Fe4N(CO)12] (Et4N-1) is a catalyst for the HER or for CO2 conversion at −1.25 V vs SCE using a glassy carbon electrode.
创建时间：
2016-02-22
