Application of the Dimensional Reduction Formalism to Pb<sub>12</sub>[Li<sub>2</sub>(P<sub>2</sub>O<sub>7</sub>)<sub>2</sub>(P<sub>4</sub>O<sub>13</sub>)<sub>2</sub>](P<sub>4</sub>O<sub>13</sub>): a Phosphate Containing Three Types of Isolated P–O Groups
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A new phosphate, Pb12[Li2(P2O7)2(P4O13)2](P4O13), containing three types of isolated polyphosphate anionic groups [P2O7], and two types of [P4O13] has been successfully synthesized by using Li2O as dimensional reduction agent to dismantle Pb3P4O13. The isolation of [P2O7] and two types of [P4O13] with different symmetries in the title compound mainly benefits from the large number and flexible coordination of the Pb2+ cations.
创建时间：
2016-07-26
