Palladium-Catalyzed Multicomponent Reaction (MCR) of Propargylic Carbonates with Isocyanides
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https://figshare.com/articles/dataset/Palladium-Catalyzed_Multicomponent_Reaction_MCR_of_Propargylic_Carbonates_with_Isocyanides/4220637
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资源简介：
A palladium-catalyzed multicomponent
reaction (MCR) of propargylic
carbonates with isocyanides is reported. Remarkably, the orderly insertion
of isocyanides affords two types of valuable N-heterocyclic
products (Z)-6-imino-4,6-dihydro-1H-furo[3,4-b]pyrrol-2-amines and (E)-5-iminopyrrolones in high yields. Systematic analysis
of the reaction conditions indicates that the selectivity of these
N-heterocyclic products can be controlled by ligands and temperature.
创建时间：
2016-11-14
