Homochiral Zn and Cd Coordination Polymers Containing Amino Acid−Tetrazole Ligands
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https://figshare.com/articles/dataset/Homochiral_Zn_and_Cd_Coordination_Polymers_Containing_Amino_Acid_Tetrazole_Ligands/3358051
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资源简介：
The reactions of (S)-3-cyanophenylalanine with NaN3 in the
presence of H2O and Lewis acids (ZnCl2 and CdCl2) afford two
unprecedented 3D homochiral networks, mono[(S)-5-(3-tetrazoyl)-phenylalaninato]zinc(II) (1) and mono[(S)-5-(3-tetrazoyl)-phenylalaninato]cadmium(II) monoaqua(II) (2), respectively. The two
compounds are isostructural with noninterpenetrated SrAl2 topology.
The structure of these coordination polymers gives new insight
into Sharpless' reaction of chiral 5-substituted 1H-tetrazole and
homochiral supramolecular array constructions.
创建时间：
2003-12-01
