Synthesis of the N(CH<sub>2</sub>CH<sub>2</sub>NCH(<i>o</i>-C<sub>6</sub>H<sub>4</sub>)PPh<sub>2</sub>)<sub>3</sub> Ligand and Its Complexation with Tungsten Carbonyls To Form a 47-Membered Cryptand-Like Metallatricycle
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Schiff base condensation of N(CH2CH2NH2)3 and Ph2P(o-C6H4)C(O)H produces the potentially heptadentate ligand N(CH2CH2NCH(o-C6H4)PPh2)3, which reacts with tungsten carbonyls to form two tripodal complexes and a tricyclic cage complex.
创建时间：
2005-07-04
