Absolute Configuration of the Polyketide Natural Product (−)-Enterocin
收藏Figshare2022-09-21 更新2026-04-28 收录
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The absolute configuration of the polyketide natural product (−)-enterocin was established by two independent approaches. In the first approach, synthetic enterocin with a defined configuration was compared to the natural product. While identical in all scalar properties, the compound displayed an opposite specific rotation and a different chiral HPLC retention time when compared with (−)-enterocin. In a second approach, the vibrational circular dichroism (VCD) of the natural product was measured and shown to be opposite to the calculated VCD of its enantiomer.
创建时间：
2022-09-21
