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Phosphaspiropentene as a Transient Intermediate

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NIAID Data Ecosystem2026-03-06 收录
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https://figshare.com/articles/dataset/Phosphaspiropentene_as_a_Transient_Intermediate/3373240
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A phosphaspiropentene is the plausible kinetic product from the addition of dichlorocarbene to a phosphatriafulvene, which rearranges to a novel P-substituted triafulvene. The calculated barrier of 18.6 kcal mol-1 for this process is consistent with the temperature of −40 °C at which this reaction proceeds.
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2016-05-12
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